Gas-liquid chromatographic analysis of free long-chain aldehydes.

نویسندگان

  • R Wood
  • R D Harlow
چکیده

Quantitative results are reported for gas-liquid chromatography of mixtures of free tetra-, hexa-, and octadecanals and cis-9-octadecenal on polar and nonpolar liquid phases. Stability of the fatty aldehydes during chromatographic analysis and up to 1 year of storage appears to be related to the solvent (carbon disulfide) used. Analysis of the free aldehydes by gas-liquid chromatography eliminates the disadvantages associated with the preparation and analysis of derivatives for this lipid class.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Free ceramide, sphingomyelin, and glucosylceramide of isolated rat intestinal cells.

Free ceramide, glucosylceramide, and sphingomyelin were isolated from mature cells of adult rat small intestine. Free ceramide and ceramide cleaved from sphingomyelin by enzymatic hydrolysis were fractionated by thin-layer chromatography on borate-impregnated silica gel plates. Sphingoid bases were characterized by gas-liquid chromatography of aldehydes formed upon periodate oxidation. Fatty ac...

متن کامل

Gas-liquid chromatography of 2-chloroethyl esters using a detector specific for halogens.

The gas-liquid chromatography of 2-chloroethyl derivatives of short- and long-chain monocarboxylic acids, and of short-chain dicarboxylic acids and aldehydes has been studied with a dual-flame ionization detector that provided simultaneous records of the concentrations of chlorine and of total organic material in the column effluent. The chloroethyl derivatives of dicarboxylic acids and aldehyd...

متن کامل

Chromatographic methods in the determination of absolute and relative configurations of fatty acids.

Chromatographic techniques for determination of configurations of branched and substituted long-chain fatty acids, both absolute and relative, are reviewed. Gas-liquid chromatographic and thin-layer chromatographic procedures are emphasized.

متن کامل

Glyceryl ether synthesis from long chain alcohols in elasmobranch stomach.

1. The isolated stomachs of the dogfish, Squdus acanthias, and the skate, Raja erinacea, were found to incorporate long chain alcohols and acetate, but not long chain fatty acids, into glyceryl ethers. 2. The criterion for evaluation of incorporation of radioactive substrates into glyceryl ethers was the measurement of activity of individual isopropylidene derivatives separated by means of gas-...

متن کامل

Atmospheric Analysis: Gas Chromatography

The determination of both naturally produced and anthropogenic organic species in the atmosphere is a key area in atmospheric chemistry research. Nearest to the earth’s surface, within the boundary layer of the troposphere, the determination of hydrocarbon species is important because of their ability to react rapidly with NOx in the presence of sunlight to form photochemical smog. At the other...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Journal of lipid research

دوره 10 4  شماره 

صفحات  -

تاریخ انتشار 1969